MCU problem for two instances of klipper

Please show the Ender log as well and the output of dmesg. For this, follow How-To Trouble-Shoot

In addition, try connecting only one printer. From the log, it seems possible that both printers are connecting via the same /dev/serial/by-id/... path. Although this would be surprising because your log shows an FTDI chip, and I have not yet seen an Ender with such a chip.